Download High- and Low-Valent tris-N-Heterocyclic Carbene Iron by Carola S. Vogel PDF

By Carola S. Vogel

Carola Vogel’s PhD thesis specializes in the synthesis, and structural and spectroscopic characterization of the 1st excessive valent iron nitride complexes. In her interdisciplinary and collaborative study Carola additionally describes the reactivity stories of a distinct iron (V) nitride advanced with water. those reviews express that quantitative yields of ammonia are given at ambient stipulations. excessive valent iron nitride and oxo species were proposed as key intermediates in lots of bio-catalytic variations, yet earlier those species have confirmed awfully tough to isolate and learn. Iron complexes in excessive oxidation states can hence function types for iron-containing enzymes to aid us comprehend organic structures or relief our improvement of extra effective commercial catalysts.

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